CLFSB - N-BUTYL ALCOHOL

Product Identification

Product ID:N-BUTYL ALCOHOL
MSDS Date:01/29/1999
FSC:NIIN:Submitter:D DG
Status Code:A
Kit Part:Y
MSDS Number: CLFSB

Responsible Party
SARGENT-WELCH SCIENTIFIC INC
911 COMMERCE ST
BUFFALO GROVE, IL 60089
US

Emergency Phone: 716-226-6177

Info Phone: 800-727-4368

Preparer: MICHAEL RASZEJA

Cage: 04TG8

Contractor
WARDS NATURAL SCIENCE ESTABLISHMENT INC
92912 ROCHESTER, NY 14692-9012 US

Telephone: (716) 359-2502

Cage: 63759

Ingredients

N-BUTYL ALCOHOL

CAS: 71-36-3

RTECS: EO1400000

OSHA PEL 300 MG/M3;100 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Hazards

LD50 LC50 Mixture:ORAL LD50 RAT: 2.5 G/KG
Health Hazards Acute and Chronic:INHALTION: VAPORS CAUSE IRRITATION TO
UPPER RESPIRATORY TRACT. HIGH VAPOR CONCENTRATIONS CAN PRODUCE
HEADACHES, DIZZINESS, DROWSINESS, CNS DEPRESSION. EYE: CONTACT WITH
LIQUID OR VAPOR CAUSES IRRITATI ON. PROLONGED AND REPEATED EXPOSURE
TO THE VAPOR MAY RESULT IN CORNEAL INJURY. SKIN: PROLONGED OR
REPEATED CONTACT CAUSES DRYING AND CRACKING OF THE SKIN, WHICH
RESULTS IN SKIN IRRITATION AND DERMITIT IS. INGESTION: HARMFUL IF
SWALLOWED. MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION, HEADACHE,
DIZZINESS AND NAUSEA.
Explanation of Carcinogenicity:NO DATA PROVIDED BY MANUFACTURER
Effects of Overexposure:INHALTION: VAPORS CAUSE IRRITATION TO UPPER
RESPIRATORY TRACT. HIGH VAPOR CONCENTRATIONS CAN PRODUCE HEADACHES,
DIZZINESS, DROWSINESS, CNS DEPRESSION. EYE: CONTACT WITH LIQUID OR
VAPOR CAUSES IRRITATI ON. PROLONGED AND REPEATED EXPOSURE TO THE
VAPOR MAY RESULT IN CORNEAL INJURY. SKIN: PROLONGED OR REPEATED
CONTACT CAUSES DRYING AND CRACKING OF THE SKIN, WHICH RESULTS IN
SKIN IRRITATION AND DERMITIT IS. INGESTION: HARMFUL IF SWALLOWED.
MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION, HEADACHE, DIZZINESS
AND NAUSEA.
Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY MANUFACTURER

First Aid

First Aid:INHALTION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
CALL PHYSICIAN. EYES: FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15
MINUTES, LIFTIN G UPPER AND LOWER EYELIDS OCCASIONALLY.GET
IMMEDIATE MEDICAL ATTENTION. SKIN: FLUSH THOROUGHLY WITH WATER, THE
WASH WITH MILD SOAP AND WATER. INGESTION: IF SWALLOWED, IF
CONSCIOUS, GIVE 1-2 GLASSES OF WATER, INDUCE VOMITING AND CALL A
PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR DROWSY
PERSON.

Fire Fighting

Flash Point Method:TCC
Flash Point:=36.7C, 98.F
Autoignition Temp:=116.7C, 242.F
Lower Limits:1.4
Upper Limits:11.2
Extinguishing Media:CARBON DIOXIDE(CO2), DRY CHEMICAL (ABC); ALCOHOL
FOAM; WATER FOG.
Fire Fighting Procedures:IN FIRE CONDITIONS, WEAR A NIOSH/MSHA APPROVED
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
COOL FIRE EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS; CAN REACT VIGOROUSLY WITH
OXIDIZING MATERIALS. CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRE
SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILD UP
WHICH COULD RESULT IN CONTAINER RUPTURE.

Accidental Release

Spill Release Procedures:WEARING PROPER PROTECTIVE EQUIPMENT, PROVIDE
ADEQUATE VENTILATION. ELIMINATE ALL SOURCES OF IGNITION. ABSORB IN
SAND, EARTH OR VERMICULITE. CAREFULLY SWEEP UP AND REMOVE. FLUSH
SPILL AREA WITH WATER. DO NOT ALLOW WASH WATER TO POLLUTE WATER
WAYS AND STREAMS.
Neutralizing Agent:NO DATA PROVIDED BY MANUFACTURER

Handling

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, FLAME. DO
NOT STORE IN COPPER OR ITS ALLOYS. WASH THOROUGHLY AFTER HANDLING.
DO NOT STORE IN ALUMINUM EQUIPMENT AT TEMPERATURES OVER 120F. KEEP
CONTAINER TIGHTLY CLOSED WH EN NOT IN USE.
Other Precautions:DO NOT WEAR CONTACT LENSES WHEN WORKING WITH
CHEMICALS. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID
BREATHING VAPORS. USE WITH ADEQUATE VENTILATION. REMOVE AND WASH
CONTAMINATED CLOTHING. KEEP O UT OF REACH OF CHILDREN.

Exposure Controls

Respiratory Protection:IN THE LABORATORY, WORK IN VENTILATION HOOD. USE
AN APPROVED ALL PURPOSE ORGANIC VAPOR CANISTER MASK FOR EMERGENCY
CLEANUP OF SPILLS, OR ATMOSPHERE-SUPPLYING RESPIRATOR.
Ventilation:LOCAL EXHAUST/MECHANICAL(GENERAL): RECOMMENDED.
SPECIAL/OTHER: NO.
Protective Gloves:RUBBER
Eye Protection:CHEMICAL SAFETY GOGGLES
Other Protective Equipment:GOGGLES, SMOCK, APRON, PROPER GLOVES,
VENTILATION HOOD, FIRE EXTINGUISHER, EYE WASH STATION.
Work Hygienic Practices:AVOID CONTACT WITH EYES, SKIN AND CLOTHES.
AVOID BREATHING VAPORS. USE WITH ADEQUATE VENTILATION. REMOVE AND
WASH CONTAMINATED CLOTHES.
Supplemental Safety and Health
THIS IS PART OF A KIT CONTAINING: 36-7008, ACETIC ACID, GLACIAL; ETHYL
ALCOHOL. DENATURED, ANHYDROUS; OCTYL ALCOHOL; N-BUTYRIC ACID;
N-BUTYL ALCOHOL; SULFURIC ACID CONCENTRATE; METHYL ALCOHOL. KIT SER
IAL NUMBERS: CLFRQ, CLFRS, CLFRV, CLFRZ, CLFSC, CLFSD.

Chemical Properties

HCC:F5
Boiling Pt:=116.7C, 242.F
Melt/Freeze Pt:=-89.C, -128.2F
Vapor Pres:4.1MM@20C
Vapor Density:2.5
Spec Gravity:0.8108@20/20C
Evaporation Rate & Reference:0.43
Solubility in Water:MODERATE
Appearance and Odor:COLORLESS, MOBILE LIQUID; STRONG ODOR
Percent Volatiles by Volume:100%

Stability

Stability Indicator/Materials to Avoid:YES
STRONG MINERAL ACIDS, STRONG OXIDIZERS, COPPER AND ITS ALLOYS. ALUMINUM
CONTAINERS.
Stability Condition to Avoid:EXCESSIVE TEMPERATURE OR HEAT.
Hazardous Decomposition Products:CARBON MONOXIDE AND UNIDENTIFIED
ORGANIC COMPOUNDS.

Disposal

Waste Disposal Methods:DISPOSE OF IN AN APPROVED INCINERATOR OR
CONTRACT WITH A LICENSED WASTE DISPOSAL SERVICE.

Toxicology

Toxicological Information:DERMAL LD50 (RABBIT): 4.2 G/KG. INHALATION
LC50: NO DEATHS AT 8000 PPM/4H (RAT).

Other Information

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecology

Ecological:NO DATA PROVIDED BY MANUFACTURER

Transport

Transport Information:D.O.T.: BUTANOLS, 3, UN1120, PGIII.

Regulatory

SARA Title III Information:NO DATA PROVIDED BY MANUFACTURER
Federal Regulatory Information:NO DATA PROVIDED BY MANUFACTURER
State Regulatory Information:NO DATA PROVIDED BY MANUFACTURER